Selected Publications
For reprints send a request to Vasyl Karabyn
V.
Karabyn. V. Kolodiy, M. Pavlyuk, R. Pankiv (2005). Geochemical paragenetic
associations of the components of edge waters in the Khidnovychi gas field.
Geology and geochemistry of combustible
minerals, 3-4, 74-82.
Edge waters of Khidnovychi
gas field have chiefly chlorite sodium, chlorite calcium-sodium, chlorite
magnesiumî-calcium-sodium and hydrocarbon-chlorite sodium composition. Other
waters (10.3 %) have the mixed "exotic" composition: sulphate-hydrocarbon-chlorite
sodium, hydrocarbon-sulphate-chlorite magnesium-sodium, hydrocarbon-chlorite
calcium-sodium and chlorite sodium-calcium.
General mineralization of waters, density of I-, ÍÑÎ3-, Â2Î3 and also metamorphosis
coefficient of waters rNa/rCl declines with the depth for the main types of
edge water. Direct correlation relationship is fixed between Â2Î3 and ÍÑÎ3-.
The phenomenon of hydrogeochemical inversion is proved. Hydrogeochemical inversion
has taken place owing to formation of sedimentogenic (lithogeneous) waters
due to change in waters mineralization of the sedimentation basins.
Dominant over Khidnovychi deposit chlorite sodium water is the habit of the
Khidnovychi gas field. Two paragenesis associations of edge water ingredients
are distinguisted in these waters. To the first belong ions of K+, Na+, Ca2+,
Mg2+, NH4+, Cl-, Br-, J-and general mineralization with increase in concentration
and amount of which naturally decreases value of metamorphosis coefficient
of waters rNa/rCl, coefficient rSO4·100/rCl and depth of selection. To another
paragenesis associations belong B2O3, HCO3-, depth of selection, SO42- and
rNa/rCl. Is fixed the regularity of an abatement of concentration of K++Na+,
Ca2+, Mg2+, NH4+, Br-, Cl-, J- and general mineralization with increase in
depth of sample drawing of water. It is proved a relative openness of aquifers
at fracture zones and a zone of a thrust of the Inner zone of the Carpathian
Foredeep on the External zone. It is proved a leading role of a thrust on
extent of a hydro-geological openness of aquifers of the Khidnovychi deposit.
Other types of sedimentary edge waters of the deposit are also characterized.
Waters of hydrocarbon-chlorite sodium composition which have condensation
genesis were fixed.
The surveyed types of waters and the paragenesis association of their ingredients
should be taken into account while deposits exploitation.
Y.Kozak, V. Karabyn, O. Stargynsky, Y. Pototsky (2005). Influence of deap-wells
drilling on environmental contamination by mineral oil in area Stryj water-fence.
Resources of natural waters of Carpathian region. The scientific collection.
67-70.
M. Triska, O. Kolodij, V. Karabyn, I. Popivnjak (2004). To the analysis
of ecological functions of lithosphere of Boryslav-Drohobych ring structure
(based on aerospace photos deciphering and processing of medical date). Visnyk
of the Lviv University. Series Geological, 18, 256-263.
Boryslav-Drohobych ring structure, complicated by longitude and cross faults of different order relatively to the Carpathians, has been diagnosed. The active and inactive faults are distinguished. It is clarified that the ruptures arcuate system (mostly active), which forms the Boryslav-Drohobych ring structure, coincides with the position of the Bystrytsia, Kolodnytsia, Detnianka rivers and villages Verhnij Dorozhiv, Urozh, Skhidnytsia, Kolodnytsia. Boryslav, Skhidnytsia, Truskavets', Drohobych, Stebnyk, Bania, Sol'na, Urozh, Verkhnia Stynava, Ulychne, Ranevychi are located in the zone of another faults that could have unfavorable influence on the health of people.
Oil, ozocerite, salt deposits are localized in the area of Boryslav-Drohobych ring structure. Their explorations have significant technogenic influence on the environment of the region. Menilite slates outcrops on the big territory and contain significant volume of the organic matters, heavy metals and have high radioactivity.
The ecological functions of
lithosphere in this district are evaluated as unfavorable for biota.
V. Kolodiy, N. Miskiv, V. Karabyn (2004). Peculiarity of formation
of man-caused condensation waters of Precarpathions gas deposits. Oil
and Gas of Ukraine. Scient. Collection. Kiev. 139-141.
I. Knysh, V. Karabyn (2004). Paragenesis associations of heavy metals
at coalheugh of Lviv - Volyn gas-coal basin's Stepova pit. Mineral resources
of Ukraine, 3, 42-44.
It is investigated waste products of coal manufacture with application of mathematical and statistical methods.
V. Karabyn (2004). Soil's ionic - saline composition of Carpathian mountain
landscape on building allotments of oil-wells. Mineral resources of Ukraine,
2, 42-43.
Well-boring
causes man-caused soil's saline. A contents and correlation of main ions in
water drawing from soil depend on contamination age, type of elementary landscape
and by presence of organic matters. In epicentres of organic Pivdennostynavska
contamination of allotment, in transeluvium position, a salting maximum is
observed in iluvium horizon. In process of peak time the saline relocate down
for cut soil and from eluvial landscape in accumulation landscape. By most
intensive pollutants there are the sodium ions and potassium, to chlorine
and sulphate ion.
V.V.
Kolodiy, N.I. Mis'kiv, V.V. Karabyn (2003). Man-caused condensate waters of
the gas pools of Precarpathians. Geology
and geochemistry of combustible minerals, 3-4, 37-43.
A long deposits gas contact
with water in liquid phase causes to bedded gas-steam phase formation. A contents
of watery steam in gas depends on gas nature, temperature and pressure. Accordingly
natural gas in beds contents some, sometimes considerable, amount of watery
steam. In External zone of Precarpathian foredeep on depth 3000 m into 1 nm3
is contained by 8 g water.
Attached to quarrying of gas his pressure and temperature in separator machine
quickly diminish. For these condition contents of watery steam in gas will
decrease, and superfluous water will condense, chiefly in gaseous separator.
The water condition, that is generated under time of technological gas output
proces is by man-caused (technogenic) condensate water (MCCW). It specific
amount depends from bedded gas saturation and from thermo-pressure parameters
of separation. Throughout to gas quarrying period pressure in bed diminishes
that for permanent temperature is attended with growth of contents in it moisture.
In bed with elementary bedded pressure for example 30 ÌÏà and by temperature
70 of wasp, that remains permanent throughout to gas selection, his saturation
will grow from 1,7 to 6,0 g/n m3. The MCCW's mineralization as a rule does
not exceed 1 g/dm3, and soluble in water substance's composition determines
by their molecular displacement into gas. A salts displacement process by
watery steam is selective. Overwhelmingly fresh MCCW by chemical composition
is other than superficial waters.
Condensation is danger for fresh water bicause content the considerable amounts
of various soluble in water organic substance. The MCCW's displacement give
rise also to complications by means of hydrates formation.
In first bed exploitation period an overwhelming MCCW's amount go out on surface,
where assists of hydrates formation. On some intermediate exploitation stage
when gas pressure in bed will decrease approximately half it saturation increases
by reason of evaporation of bedded outline or underlayer water in zone of
gas-watery contact and also residual layer-collector water, a contents of
which can reach to 60 % pore space's volume. By reason of underestimation
of temperature in depression watering-can for big pressure overfalls water
will condense and on well bore, however her amount will be insignificant and
it will go out by gas stream and will accumulate in separators and gas mains.
On final bed exploitation stage on measure a fall stratum pressure saturation
of gas will increase. Energies to gas stream can be insufficiently for go
out from well bore all MCCW and water will flow down, forming a watery cork.
MCCW upcast into superficial reservoirs is inadmissible so MCCW need clearance
that hike expenses on gas output and can do it unprofitable. Most expedient
in economic and environment protection aspects there is an interment of these
waters in outline zones of exhausted gaseous and petroleum beds. Specially
favourable interment of such waters in outline domains of gas dug-outs created
on work out gaseous beds.
R.J.
Leshchukh, V. V. Karabyn (2003). Doctor of sciences (geology), professor Volodymyr
Vasyliovych Kolodij scientist and patroot. Visnyk
of the Lviv University. Series Geological, 17, 159-164.
Biography of famous Ukrainian
scientists, Doctor of geological-mineralogical sciences, Head of Ukrainian
national committee of Carpathian-Balkan geologic association, Head of Geologic
commission of Shevchenko Scientific Society, Professor of Ecological and Engineering
Geology and Hydrogeology Volodymyr Vasyliovych Kolodiy is presented. The analysis
of the most important scientific publications is made. Full
text
V.
V. Karabyn, I. B. Knysh (2003). Ecological-geochemical description of coalheugh
of Lviv - Volyn gas-coal basin's Stepova pit. Geology
and geochemistry of combustible minerals, 2, 139-146.
To basic ecological problems
of Chervonohrad coal district belong earthed of territory, changes of geochemical
fields, contamination of soil, water and air, formations of man-caused's landscape
by dint of forming of coalheughs, settler.
As research object by us select "Stepova" pit (to 2001 y. Velykomostyvska
¹ 10) but specifically it coalheugh, which is found on distance 400 ì more
east pit. It is fully disposed on alluvial Solokia river. A coalheugh base
area composes 165 300 ì2, middle height 22 t. In coalheugh heaped up 4,475
mln. ì3 coal culm unburnt rocks. On slopes coalheugh is reinstatement.
By authors explored litological, pitral coalheugh surface rocks storage and
their radio-activity. By spectral analysis expressed a contents Sr, Mn, N³,
Ba, Pb, I, Cu, Zr, Sn, Cr, Mo, Zn, Ge, Co in coalheugh rocks mixture. Set,
that rocks to pit dump Steppe represented, mainly argillite (78 %) and lesser
alevrollite (7 %), by sandstones (8 %) and coally rocks (2 %). Set straight
dependence between amounts of coally material and alevrollite (correlation
coefficient r=0,72) and sandstones (r=0,36) in superficial coalheugh layer
(0-0,2 m). Amount of coally material (Qâì) and contents argillite (Qà) abide
in reverse dependence, that describes by Qâì = 11,0 0,1 * Qà. A coalheugh
rocks mixture ash vacillates from 66,6 to 79,4% and on a par composes 79 %.
Rocks mixture Radio-activity on distance 0,2 m from surface vacillates from
7,3 to 20,6 mR/h and on a par is 16,2 mR/h, that is not dangerous for living
organisms.. On height 1 ì over surface radio-activity (R) vacillates in boundary
paths from 6,8 to 18,9 mR/h on a par composes 15,2 mR/h and her senses controls
by thickness of coalheugh layer (Íl): R = 17,8 7,7 * Íl . Rocks to Stepova
pit dump by generally have is small content Sr, N³, Ba, I, Cu, Mo, Ge, Co
weighed with coal and argillite from coal leyer. In raised rock concentrations
to dump contain only That and Zr. Concentration Sr, Mn, N³, Ba, Pb, I, Cu,
Zr, Sn, Cr, Mo, Zn, Ge, Co in coalheugh rocks does not exceed considerably
their contents in soil. Information analysed by authors does not disclaim
a pit coalheugh rocks use possibility Steppe as building or ahrochemical material.
Same warning is brings on Ti contents. For definitive rocks payment safety
estimation to dump in soil region necessary to see out research of circulating
in soils and to set the finding forms to titan in pit rocks. Necessary also
to learn diffusion in rocks to Li, Be. Into which in raised amounts are contained
in Lviv - Volyn gas- coal basin.
Karabyn V. (2002). Classifying
the sources of pollution of Transcarpathian's territory for the oil well's
construction. Geologica Carpathica. ISSN 1335-0552 (CD).
Bratislava,
vol. 53.
The basis
reasons of environmental pollution during the work execution for oil and gas
in the work are analysed. Classification
of the sources of pollution taking oil-gas-exploratory wells of Boryslav-Pokuttya
subzone of the Precarpathian, foredeep as example is made. Three classes:
natural, man-caused and man-caused-natural are distinguished. Full
text
Karabyn V. (2000). Theoretical - methodical aspects of regional evaluation
of geological medium state in the areas of hydrocarbon exploration and production.
Mineral resources of Ukraine, 2, 11-13.
Oil and gas wells parallel
with fulfilment of theirs direct geological tasks in time became the factors of
ecological risk in Ukraine territory. Taking into account possible complicated
and dangerous ecological - geologicalsituations caused by destruction of old
and construction of new wells, the question of these processes management on
the grounds of system method of approdeh presents a very important problem .
Research necessarity of
developing which of “kagsemp” bore-holes for gas and oil , ecological and
geochemical “çéîìêó”of the greatest types geological systems of technical
origin, systematisation , generalisation of received results , making the plan
of taking natureprotecting measures for control of the geological surroundings
.
Karabyn V., Toorkevych L., Yarontovsky O. (2000). Oil-chemical contamination
of the near-surface hydrosphere of Ukraine and its ecological-geochemical
consequences (at the example of the Precarpathian areas). Mineralogical
Collection, 50, 124-129.
The results of ecological-geochemical investigations of technogenic
influence of the deep oil-gas wells construction upon the near-surface
hydrosphere of the Inner zone of Precarpathian deep are given. Analytical
investigations established the stable presence of oil products and phenols in
dangerous quantities in drilling waste, drilling mud and the components for its
preparation. They are spread in the environment because of the violence of the
nature protection demands and pollute the waters of the surface reservoirs,
rivers, and also are being filtered into the underground horizons.
Karabyn V., Toorkevych L., Yarontovsky O. (1999). Peculiarities of the
change of salt composition of the meadow soil of the Precarpathians in connection
with the oil well drilling. Visnyk of Lviv University. Series Geographical,
25, 59-61.
The investigation was carried out
within the Blazhiv-Monastyrets ecological-geochemical proving ground, whose
subsurface hydrolithosphere was polluted with oil products and phenols. A
number of peculiarities was established in the change of salt composition of
the meadow soils and bottom deposits of the ditches and ravines in connection
with the oil well construction. The salt composition of the samples was
determined the water extracts.
Yarontovsky O., Karabyn
V. (2000). Petrochemical pollution of near-surface waters both problem of its
detection and liquidation. Scientific visnyk of NMA, 3, 59-61.
The researches of the
specifications of Striy territories adjoining arranged to a water intake of
potable waters and group of oil-fields Pricarpatians are conducted.
The complex of geochemical
researches, nature protection technologies of oil and gas works, methods of
detection and liquidation of petrochemical pollution is recommended.
Karabyn
V., Yarontovsky O., Matsulyak I. (1999). Ecological-geochemical investigations
of the of the oil wells constructions influence upon the near-surface hydrolithosphere
of the Precarpathian. Geology and geochemistry
of combustible minerals, 2, 94-100.
In 1997 the Ukrainian State
Geological Research Institute had carried out the complex of
ecological-geochemical investigations of technogenous influence of processes of
the oil wells drilling and operation process upon natural conditions of
Blaghiv- Monastyrets proving ground near-surface hydrolithosphere. On the basis
of upon the natural conditions of the laboratory estimations by the methods of
infrared and ultraviolet spectrofotometry in the drilling waste and the
components of natural medium the high content of petroleum products and phenols
are established. In consequence of the petroleum products and phenols which are
found in drilling mud and in quantity to 181,2 and 19,5 mg/dm3 correspondingly
pollute the near-surface hydrolithosphere. The migration of contaminant
substances is determined mainly by surface discharge, accumulation, sorbtion
and connective filtration.
Karabyn V., Jarontovsky O.,
Toorkevych L. Paragenesis of the microelements in pollutants at the oil-gas
wells construction. Abstracts volume of the Mining Pribram symposium. Prague,
October 4-8, 1999, P. MA 20.
In particular, the content of heavy metals was
determined by spectrofluorense method in drilling slimes, drilling muds and
separate components for their preparation : bentonite clay, hematite, oxidated
bitumen and others. The obtained data were generalized into a single extract of
microelement composition of drilling slimes, muds and their components. The
matrix of summary content of Cr, Mn, Fe, Co, Ni, Zn, Pb, Cu, which was composed
taking into consideration the mineral composition of drilling muds and waste,
underwent the system processing by the method of main components. And in the
result two main paragenetic associations of microelements were established :
siderophile ( Fe, Ni, Co, Cr ) and chalcophile (Pb, Cu, Zn ).
Main conclusions of the investigation : 1. The
supplier of the siderophile association elements into the drilling muds and
waste is hematite powder. 2. The source of the chalcophile association elements
is oxidated bitumen . 3. The significant part of Cr enters the drilling muds
and waste from potassium bicromate, the less one — from oxidated bitumen and
hematite. 4. Mn, which does not belong to any of the described associations of
microelements, is contained in bentonite clay in high quantity. 5. Violation of
the nature protection measures at the oil-gas wells construction leads to the
environment pollution of the Precarpathian by toxic heavy metals of the
investigated groups.
Sysa L.V., Hubych I.B., Bekesha N.V., Karabyn V.V. (1999). Statistical
interpretation of geochemical investigations results on the Northern edge
of Dniper-Donets Depression. The new data on geology and oil-and-gas-boringness
of Ukraine: Coll.of scientific articles. Lviv: UkrDGRI, 197-204.
Basing on the method of analogies the rating
system of estimation for processing the results of geochemical and other
investigations is worked out. It operates with concrete experimental data,
partly explains their interdependence of the local areas of the Northern edge
of Dniper-Donets depression are calculated. They characterize the probability
of hydrocarbon pools discovery.
Karabyn V., Jarontovsky O., Bila L. (1998). Modelling of the contaminants
spatial distribution in the subsurface hydrolithosphere of Southern Stynava
oil field. Abstracts of The Forth International Symposium “Application of
Mathematical Methods and Computer Technologies in geochemistry and Environmental
Protection”, Kiev, 48-49.
Hubych I., Karabyn V. (1996). The forecast oil field in soil behind the
contents of mercury determined X-rey-fluorescence method. Mineral resources
of Ukraine, 4, 32.
On
the basement of X-rey-fluorescence method the waus of investigation of mercury
microconcentrations in the soil during exploration works on oil and gas. The
method are based on the copre cipitation of mercury on cadmium sulphide during
passing through the investigated solution of hudrogen sulphide. The sensitivity
of determination is 0.5 mcg of mercury (the tension of X-rey tube is 40 kV).